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Photosynthesis is a redox process. It uses energy to reduce CO2 and form glucose. Light energy boosts the energy of the electrons in H as they move from water to sugar. Sugar is made when water molecules are split and electrons are transferred from the water to carbon dioxide.
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Photochemical redox catalysis is a rediscovered field of activation for many reaction pathways and will probably replace many traditional photochemical routes that produced thermal waste and open new routes to synthetically valuable products of photocycloaddition reactions.
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The table is set up so that the reduction potential increases as you move up the table in a spontaneous redox reaction the higher half reaction on the table will be the reduction.
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